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Yu. Ya. Kuzyakov, E. N. Moskvitina
Intracavity laser spectroscopy of intermediate
chemical species in gas phase. monoxides and mononitrides of transition metals.
Abstract
An intracavity laser method for obtaining the
multiline electronic spectra of intermediate chemical species has been
developed. This method has been applied to study the absorption stectra of
monoxides and mononitrides formed by interaction between the tetrahalides of transition
metals with oxygen and nitrogen. Kinetics of monoxide and mononitride formation
has been studied. New bands have been detected and recorded in their
electronic- vibrational- rotational spectra. This result has enabled the
calculation of molecular constants which have not been known hitherto.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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