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Rostovshchikova T. N., Kiseliova O. I., Yurkov G. Yu., Gubin S. P., Pankratov D. A., PerfilievYu. D., Smirnov V. V., Chernavskii P. A., Pankina G. V.
Catalysis of Allyl-like Chloroolefin
Reactions by Nanosized Iron Oxides
Abstract
Nanosized particles
of iron oxides (Fe2O3, FeO, Fe3O4)
catalyze reactions with allyl chloroolefin participation, in particular
isomerization with double bond and chlorine atom migration and aromatic
hydrocarbon alkylation. Catalysis efficiency and reaction direction depend on
the oxygen presence. The other factors determining catalytic properties of
oxides are the iron oxidation state and
the nature of the nearest surrounding of nanoparticles.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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