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L. V. Serebrennikov, A. V. Golovkin
The reaction between formaldehyde
and hydrogen peroxide. IR- spectra in xenon matrixes and calculations of
intermediates and transition states
Abstract
Products of reaction
between formaldehyde and hydrogen
peroxide were investigated in low temperature matrixes of xenon and in gas
phase by the method of IR – spectroscopy. Calculations of intermediates and stable productes by
D.F.T were carried out. Saddle pointes
for elemental processes were also calculated. It is shown that the reaction
between formaldehyde and hydrogen peroxide corresponded as 1:1, 1:2, 2:1 forms one intermediate H2C(OH)OOH.
It decomposes using a few channels close activation energy.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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