|
N. A. Rezekina, E. V. Rakhmanov, E. V. Lukovskaya, A. A. Bobylyova, V. A. Chertkov, O. V. Kostyuchenko, A. A. Abramov, A. V. Anisimov
Oxathiacrown-ethers Based
on 2-Allylanisole and 1-Allylnerolin
Abstract
12- and 15-Membered
substituted dioxathiacrown ethers:
8-[(2-methoxy-1-naphthyl)-methyl]-1,4-dioxa-7,10-dithiacyclododecane, 11-[(2-
methoxy-1-naphthyl)-methyl]-1,4,7-trioxa-10,13-dithiacyclopenthadecane and
11-[(2-methoxyphenyl)methyl]-1,4,7-trioxa-10,13- dithiacyclopenthadecane were
synthesized by reaction of 1-(2,3-ditosyloxypropyl)-anisole and
1-(2,3-dibrompropyl)-2-methoxynaphthalene with 1,8-dimercapto-3,6-dioctane and
1,11-dimercapto-3,6,9-trioxaundecane. Extraction ability was defined to Ag (I)
and Cd (II) cations for the first compound.
Copyright (C) Chemistry Dept., Moscow State University, 2002
|
|
