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E. K. Beloglazkina, N. S. Dubinina, A. A. Moiseeva, N. V. Zyk
Complexes with
amino- and iminocyclohexyl sulfides. synthesis and electrochemical
investigation
Abstract
The Ni(II)
complexes with aminosulfide and iminosulfide type ligands were synthesised on
the base of phenyl- and ethynyl-(2-aminocyclohexyl)sulfides, glyoxal hydrate,
and Ni(ClO4)2.6H2O. The
electrochemical measurements for the obtained complexes were carried out using
CVA and RDE techniques. It was shown that (1) the reduced forms for the
iminosulfide type complexes are more stable that the reduced forms for the aminosulfide
type complexes; (2) complexes, having CºC-fragments in the organic ligands, are polymerize in
the process of reducing.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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