|
A. F. Prokhorova, M. A. Kuznetsov, Ye. N. Shapovalova, S. M. Staroverov, O. A. Shpigun
Enantioseparations of N-blocked
amino acids by capillary electrophoresis using macrocyclic antibiotics
Abstract
The macrocyclic antibiotic eremomycin has been evaluated
as a chiral selector for the separation of the some N-blocked amino acids. To
obtain efficient separation, the effect of varying buffer parameters, chiral
selector concentration, capillary length, and applied voltage has been
investigated. The comparison of the vancomycin- and eremomycin-based
enantioseparations of dansylated amino acids has been made.
Copyright (C) Chemistry Dept., Moscow State University, 2002
|
|
