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Georgy V. Lisichkin
On a
possible reason for the predomination of vanadium in the microelement
composition of sulfurous oils
Abstract
In accordance with the abiogenic hypothesis
of the origin of oil, deposits formed as a result of degassing of the Earth, in
particular, due to the interaction of mantle methane and its polycondensation
products with elemental sulfur, are thermodynamically open systems. In open
systems, self-organization processes are realized and a progressive evolution
of the catalyst of the basic reaction occurs, accompanied by an increase in its
activity and accumulation in the system. The predominance of vanadium in the
trace element composition of sour oils may be due to its catalytic activity in
the basic reaction of the formation of C-S bonds.
Key words: open systems, chemical evolution, basic reaction,
sour oil, vanadium, porphyrinates, abiogenic synthesis
Copyright (C) Chemistry Dept., Moscow State University, 2002
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