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A. V. Golovkin, N. A. Uvarov, L. V. Serebrennikov, V. F. Shevel’kov
Interaction
of Methane with Hydrogen Peroxide in the Xenon Matrixes
Abstract
Products
of reaction between methane and hydrogen peroxide were investigated in low
temperature matrixes of xenon by the method of IR-spectroscopy. It was shown
that the first product of matrix reaction without a catalyst was a low
connected complex 1:1. It slowly transformed in formaldehyde and water at 78 K.
The use of Ni clasters as a catalyst gave a big number of absorption bands in
IR-spectra in a few hours at 78 K. These bands were assigned to different
peroxide intermediates.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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