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Yu. N. Bubnov
Allyl
Boranes: Principles of Reactivity and Application in Organic Synthesis
Abstract
All the known up to date reactions
(ca. 40) of allylic organoboranes have been systematized and divided into six
types. Three most important allylborane reactions have been considered:
allylboration of organic compounds with multiple bonds, allylbor-acetylene
condensation and reductive mono- and trans-a,a'-diallylation of aromatic
nitrogen heterocycles. Application of the above reactions to organic synthesis,
including the total synthesis of natural and related compounds, is discussed.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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