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V. V. Utochnikova, O. V. Kotova, N. P. Kuzmina
The
yttrium heteroligand complex with dipivaloilmethane and N,N¢-disalicylideneethylenediamine
(Y(dpm)(salen)) synthesis
Abstract
The heteroligand complex Y(dpm)(salen) has been synthesized
in the vapor phase and in the solution via the reaction between yttrium
dipivaloylmethanate (Y(dpm)3) and
N,N’-disalicylideneethylenediamine (H2salen). The
product composition was confirmed using the IR spectroscopy, 1H NMR and
elemental analysis. It was shown, that the total exchange reaction with
formation of Y2(salen)3 is not promoted
by the Schiff base abundance either in the solution, or in the vapor phase.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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