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T. V. Yankova, P. V. Melnikov, N. K. Zaytsev
Chemiluminescent
reaction of N-octyl luminol with hypochlorite-ion in micellar medium
Abstract
The effect
of surface-active substances (surfactants) of different charges and different
hydrocarbon radical lengths on the intensity and kinetic features of the model
chemiluminescent reaction of the hydrophobic analog of luminol – N-octyl
luminol was studied. The influence of the solution pH, the charge, the
structure and the concentration of surfactants on the intensity of
chemiluminescence and the kinetic parameters of the chemiluminescent reaction
is discussed.
Key words:
chemiluminescence, micellar systems, luminol, luminol analogue, hypochlorite
ion, surfactants.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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