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Mikhail Ya. Melnikov, Oleg I. Gromov, Vladimir I. Pergushov, Daria A. Pomogailo, Ivan D. Sorokin
Photochemistry
of methyl formate radical cations in frozen CFCl3 matrices
Abstract
Abstract. A novel mechanism has been discovered for the phototransformations
of methyl formate radical cations (RCs) wherein an RC that is furnished upon
thermally induced 1,2-transfer of an hydrogen atom in the methyl group to the
bridging oxygen atom undergoes photoinduced H+ transfer to the
matrix.
Key words: methyl formate radical cations, photochemistry, freon matrices,
reaction mechanisms
Copyright (C) Chemistry Dept., Moscow State University, 2002
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